Bis(bicyclo[2.2.1]hept-5-ene-2-carboxylato)-1κ2 O,O′;4κ2 O,O′-di-μ2-chlorido-1:2κ2 Cl;3:4κ2 Cl-octamethyl-1κ2 C,2κ2 C,3κ2 C,4κ2 C-di-μ3-oxido-1:2:3κ3 O;2:3:4κ3 O-tetratin(IV)
نویسنده
چکیده
In the title compound, [Sn(4)(CH(3))(8)(C(8)H(9)O(2))(2)Cl(2)O(2)], the tetra-nuclear complex mol-ecule has crystallographically imposed inversion symmetry. The coordination polyhedron about the two central Sn atoms is distorted trigonal-bipyramidal, whilst the two peripheral metal atoms bonded to the carboxyl-ate groups have a distorted octa-hedral coordination geometry. In the crystal, mol-ecules are connected by long Sn⋯O contacts [3.139 (11) Å], forming chains along [011].
منابع مشابه
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